Initial Post: 05_22_2008; Update
Post: 05_28_2008;
Update Post: 05_30_2008; 06_23_2008; 07_16_2008
The concentrations of the
atmospheric greenhouse gases - carbon dioxide, methane and water
vapor - are undergoing net increases even though the concentration
of water vapor is somewhat occasionally tempered as a result of
rainfalls. Moreover, any interactivity-impact such as generic
atmospheric reactions between the constituents gases, and photolytic
reactions between the same gases that may be ignited by lightening,
also would not suffer mitigation unless the concentrations of these
gases are reduced significantly. In effect, the
net impact of the
greenhouse gases effect is fully felt by planet Earth.
In recognition of this situation,
engineering and natural scientists have been working at developing
technologies for mitigating the effect of greenhouse gases, GHG.
Evolving from these development efforts are technologies that aptly
are GHG
Emission Reduction Technologies. These provide immediate solution to
the problem of GHG emission by adapting current energy generation
technologies to emit less GHG than otherwise.
GHG Emission Reduction Technologies
Almost all the technologies aimed
at reducing GHG emission have focused on reducing the emission of
carbon dioxide, while with respect to methane there is the global
push by the World Bodies to stop gas flaring all over the world.
Two technologies have been
developed specifically to accomplish the goal of reducing carbon
dioxide emission. One technology approaches the carbon dioxide
emission by undertaking carbon dioxide sequestration. The other
technology approaches the carbon dioxide emission reduction by
chemical reaction.
A third option however, that has
not received much attention, is a throw back from the 1950s
chemical operations of Monsanto, the Monsanto GHG Reduction
Technology, as dubbed from hereon.
The carbon dioxide sequestration
technology aims to store the gas under conditions of such high
pressure in which the gas exists in a liquefied state and therefore
not get discharged into the atmosphere; and with respect to the
implementation of this technology, several but all related,
approaches have been developed, and each one accomplishes the
objective of storing the carbon dioxide gas under conditions of such
high pressure that the gas exists in a liquefied state.
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Given the object of the approach
as liquefaction of combustion effluent stream carbon dioxide, the
efforts are focused first on the development of systems for
capturing CO2 from coal-fired power plants. CO2 capture is the
separation of CO2 from emissions sources or the atmosphere and the
recovery of a concentrated stream of CO2 that is amenable to
sequestration or conversion. In this regards, several different
techniques involving the adoption of chemical sorbents, physical
sorbents, membranes, hydrates, aqueous amines and other
approaches, are being researched on an on-going basis.
However, at the moment, aqueous
amines are the state-of-the-art technology for CO2 capture for PC
power plants. The technology however is still proprietary but an
off-cuff consideration should suggest the process equipment to
include the following
Packed Bed Separator
Equilibrium Flash Still
together with other ancillary
equipment as may be determined through research. In any event, the
amine solution enables large volume absorption of carbon dioxide
which is then desorbed from the amine solution when pumped into the
Equilibrium Flash Still. The carbon dioxide gas from the Equilibrium
Still is then compressed to pipeline pressure (1,200–2,000 Ibs/si (psi))
The process can then be set up as a continuous operation.
The chemical reaction driven
reduction of carbon dioxide reduction entails the deployment of
GreenFuels Technologies bioreactor(s) over the discharge
sections of the flue gas of the current technologies. The
bioreactors are rows of fat, clear plastic tubes, each with green
algae support inserted inside. With appropriate deployment or
retrofitting of the bioreactors to the effluent stream flue gas, the
flue gases flows through the bioreactors, the CO2 is consumed by the
algae as the flue gas bubbles through the tube and the algae
spacing, and oxygen is released by the algae. The relatively cleaner
flue gas bubbles skyward, but with 40% less CO2 and 86% less nitrous
oxide.
The algae grow quickly from the
generous doses of CO2-laden emissions, fed to them, and are set to
be harvested daily; the harvest is used as feed to an
algal biodiesel
process to produce biodiesel, a clear, slightly yellowish liquid. The dried green flakes
residue of the biodiesel process is proposed to be further processed
to create ethanol, using
GHG Emission Abatement
Technologies.
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The third and least exposed
method is even more beneficial: In the 1950s Monsanto Corporation
had this technology for
capturing the greenhouse gas, carbon dioxide, and used it as feed
for producing Aspirin. Obviously this process provides an
immediate win-win situation for everybody: For one thing, the GHG
emission is reduced, there is no immediate energy hardship for
businesses, and the pharmaceutical industry gets to produce aspirins
and possibly other intermediary chemicals for other medications: The
greenhouse gases from the current energy production sources are
captured directly from the discharge and used as feed for
pharmaceuticals chemicals. In such method should possibly lead to
lower cost medications, that can be made available for the third
world countries.
Clearly this is an excellent
development because while not taking away the steam of
adopting an alternative energy, the current form of energy
production can be sustained, as deliberation goes on and rather
judicious decisions are being made about the most efficacious
energy source to be adopted in replacement of the
fossil
fuel energy sources, and which ironically provides immediate
financial benefits as well.
The application of the Monsanto
GHG Reduction Technology - as is dubbed hereon forward - should also
not have too many impedances, given that the intellectual property
rights associated with it, has most probably expired, and as such
modification of the concept upon purchase from Monsanto should be
possible.
Impact of Reduction
Technologies
Each approach however has it
attendant problems that needs addressing as well.
Regarding carbon dioxide
sequestration, analysis of
CO2 capture and compression using amines raises the cost of
electricity from a newly-built supercritical PC power plant by 84
percent, from 4.9 cents/kWh to 9.0 cents/kWh. Furthermore, this
post-combustion capture of CO2 poses the development of a
challenging application because:
- The low pressure and dilute
concentration of the carbon dioxide necessitates treating an
actual large volume of gas.
- Impurities in the flue gas
tend to reduce the effectiveness of the CO2 adsorbing processes
- Direct compressing of
captured CO2 from atmospheric pressure to pipeline pressure
(1,200–2,000 Ibs/si (psi)) represents a large parasitic load.
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