|
More Update Post: 06_08_2008
A catch phrase for all
combustible energy sources excluding the fossil fuels and hydrogen,
combustibles as used in the context of world energy issues includes
alcohols: Methanol, Ethanol, Propanol and Butanol; and Biodiesel fuels.
These energy sources are in fact derivative products, as they are
not naturally occurring substances.
Methanol Production is
produced by two common methods: The old fashioned Destructive
Distillation and
Synthesis Gas Reaction Process. Synthesis gas‑a mixture of
carbon monoxide, carbon dioxide, and hydrogen‑that is usually made
by steam reforming of natural gas. A third proprietary method
under development is the Hydrogenation of Carbon Monoxide.
The
Synthesis Gas Reaction Processes currently employed for methanol
production use either high‑pressure or low‑pressure technology: In the high‑pressure process, the
synthesis gas mixture is reacted at pressures of about 300 atm, In the low‑pressure
process, the the synthesis gas mixture is reacted at pressures of
only 50‑100 atm and is catalyzed with a highly selective
copper‑based compound; however, the low‑pressure process has become
the preferred technology because of the lower natural gas feedstock
requirements and significantly lower operating costs.
Ethanol commercial production using either the wet mill process
or dry mill process. Wet mill process involves separating the grain
kernel into its component parts (germ, fiber, protein, and starch)
and feeding the starch for fermentation. Dry mill process involves
the grounding of the entire grain kernel into flour and then feeding
the flour for fermentation. In either case, the starch is converted
to ethanol during the fermentation process, creating carbon dioxide
and distillers grain.
Newer approaches, however, have
been developed: Two approaches are currently
being pursued assiduously for commercial production of ethanol:
Grain Ethanol, and Grass [Cellulosic]
Ethanol, a Third approach potentially efficacious in the tropics only is
Palm Ethanol.
|
The cellulosic ethanol
process technology basics is not significantly different from the
technology for grain ethanol except for the
preprocessing of the cellulose of the grasses. Propanol and Butanol
productions have also been well-documented in several chemistry
texts and now even the bio-community has developed methods and
processes as an Internet search will show.
The commercial production of
diesel is usually not deliberately planned for but rather is
produced as a general product component of the Fischer Tropsch
Process. The
petroleum-based diesel is composed of about 75% saturated
hydrocarbons of all isotopes and cyclohydrocarbon, and 25% aromatic
hydrocarbons including alkyl-aromatics.
Generally, the average chemical formula for common diesel fuel is C12H23,
ranging from approx. C10H20 to C15H28.
However, bio-diesel approach has also been developed: The bio-diesel process
is often based on a direct map of the
process
chemistry into a
biotechnology process and is truly based on renewable resources
in proposing even to use methanol produced with a
Methanol Bioprocesses.
Although in each of the above
processes, the essential steps have been discussed, there are
ancillary steps that must be considered including extensive chemical
kinetics studies and
analysis may be required.
Energy Type
The energy form of combustibles is chemical, being released upon the
reaction of the combustible with oxygen, with results such obtains
through the breakage of chemical bonds. The reaction gives off heat
and is of the class of chemical reactions generally termed
exothermic reaction. During the reaction enough oxygen reacts with
the combustibles such as
to completely convert the carbon atoms into carbon dioxide and
the hydrogen atoms into water molecules in vapour state.
Energy Adoption
Given portability of the combustibles, and that the reaction of the
combustible and oxygen gives off heat the approach to adopting the
energy of the combustible depends on the use-needs: The
|
combustible is reacted with oxygen and the product of steam
and carbon dioxide simultaneously heated with the exothermic heat to
support the mechanical extraction of work
as fuel for automobiles,
The
Power-Utility Generation Systems in which
combustible is reacted with oxygen to heat water to produce steam in
some form of boiler or steam generator and to then
drive a turbine with the steam to produce electricity.
An Energy Adoption-Technology Analysis, presents for consideration
two situations for the production of steam: The
Aspirated Fired Burner combustion of the combustibles, The Aspirated
Ignited reaction Combustion of combustible. The specifics and engineering designs
incorporating these two approaches have been many.
The development of Power-Utility Generation Systems, of
course, must consider the best method of storage of the combustibles
because of the high volatility of some combustibles.
The Aspirated Combustion Burners
generally have the standard design as for Coal energy Source
adoption, except for the minerals processing steps. This is the
preferred approach for most large scale power generation operations.
Power station burners simply blow combustibles as fine aerosol mist
together with oxygen into the
combustion chamber in which ignites the reaction. Obviously, the mixing of fuel and
air is much better with aerosol mist and the combustion reaction
is both quicker and cleaner. The Aspirated Fired Burners
generally have the combustible actually aflame with the water being
heated with the heat from the high temperature flame.
|